Guys,
this has just been posted on the nmap mailing list
After promising you a book on Nmap for years, I'm delighted to finally
announce the release of Nmap Network Scanning! It contains everything
I've learned about network scanning from more than a decade of Nmap
development, plus some bad jokes and (over Time Warner's written
objections) pictures of Trinity hacking the Matrix

. Here is the
abstract:
Nmap Network Scanning is the official guide to the Nmap Security
Scanner, a free and open source utility used by millions of people
for network discovery, administration, and security auditing. From
explaining port scanning basics for novices to detailing low-level
packet crafting methods used by advanced hackers, this book by
Nmap's original author suits all levels of security and networking
professionals. The reference guide documents every Nmap feature and
option, while the remainder demonstrates how to apply them to
quickly solve real-world tasks. Examples and diagrams show actual
communication on the wire. Topics include subverting firewalls and
intrusion detection systems, optimizing Nmap performance, and
automating common networking tasks with the Nmap Scripting Engine.
More Here:
http://nmap.org/book/Definitely on my Christmas wishlist.
<edit>
my cut&paste skills are lacking: part of the book is freely available online.
http://nmap.org/book/toc.html </edit>