As Don have already explained, you need to get some email samples as an attachments, and study them carefully to see if the case was email spoofing, or if they are really using some of your infrastructure as slimjim100 have pointed one example. I have seen this happen in the past using broken cgi scripts such as formmail, if any of your publicly accessible servers can act as open proxy/relay of some sort, they can use your ip addresses as the originating addresses, and the email spoofing is much easier then. first invest in investigating how this is done, what was exploited, and whom is responsible for it. prove that you can trace it back, and contain the problem, you can google for incident handling, or email fornesics if you can not afford to hire a security consultant
